Chemistry at UNC Chapel Hill
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Max Berkowitz
Joseph DeSimone
Greg Forest
Sergei Sheiko
Edward Samulski
 
  Rubinstein Group Research Projects
   
  Charged Polymers
   
  Charged polymers are important because most biopolymers (e.g. DNA and proteins) and synthetic water-soluble polymers are charged. We study properties of charged polymers in solutions, in gels, and in self-organized structures.

http://dl9s6.chem.unc.edu/ad-pres1/index.html

 
 
   
  Polymeric Surfactants
   
  Polymers consisting of blocks that "like" solvent and other blocks that "do not like" solvent often self-associate into micelles with blocks of the former type forming corona and protecting core of blocks of the latter type. These micelles are used in many of industrial processes, including polymerization and cleaning. We would like to develop a quantitative understanding of the size and the shape of these micelles and their ability to incorporate other molecules into their cores.
   
 
   
  Dynamics of Structured Fluids
   
  Interactions between molecules often lead to the formation of structure in fluids (e.g. mesophases in block copolymers or ordering of liquid crystal polymers) that has profound effects on viscosity, relaxation time, and other rheological properties. We construct molecular models to describe the dynamics of these structured fluids.
   
 
   
  Polymers at Interfaces
   
  Our goal is to understand the microscopic origin of polymer adhesion and friction. We also develop models to describe polymer adsorption and the effect of an interface on chain motion.
   
 
   
  Polymer Networks
   
  Polymer networks constitute a unique state of matter combining both liquid and solid properties. We study the formation of networks and their properties, such as network elasticity and swelling.
 
 
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Department of Chemistry
Campus Box 3290
Caudill and Kenan Laboratories
The University of North Carolina at Chapel Hill
Chapel Hill, NC 27599-3290 USA
Phone: (919) 843-7100

 

Last Updated: January 17, 2007
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