Our research group focuses on the design and synthesis of polymers and
the design and fabrication of polymer composites. We utilize unique
approaches to address the continued need for new materials with
advanced properties. In line with these priorities, the research
explores a broad range of topics from polymer/quasicrystal composites
to high performance polymers to functionalized elastomers to our
newest interest, functionalized biomaterials. The first project
in the group, the design, fabrication and study of polymer quasicrystal
composites is an exciting, growing area. Our group was the first
to produce these unique composites that combine the low surface
energy, high hardness, high scratch resistance, and high thermal
stability of quasicrystals with the well-known processing techniques
of polymeric matrices. The potential increase in the lifetime of
prosthetics such as hip joint replacements, as well as in other
low wear mechanical part applications, is tremendous.
The second project in the group addresses a materials problem with
a synthetic methodology approach. A lack of functional group
versatility, poor processing, difficult synthetic techniques,
molecular weight limitations, poor film-forming ability are a
few of the problems which have plagued thermally and mechanically
stable materials. Our group utilizes metal-catalyzed coupling
reactions to overcome many of these obstacles and lead to new
materials that have a unique combination of properties including
flame retardance, excellent insulating ability, film-forming
ability, and water and organic solvent resistance.
Finally, the group seeks to design and prepare new materials
using functionalized diene-containing monomers. This research
opens the door to the formation of polymers to be used as adhesives,
elastomers, blend compatibilizers, coatings, etc. In addition,
the most recent work in the group utilizes many of these compounds
to synthesize new functionalized biomaterials with target applications
in drug delivery and gene therapy. The ability to attach targeting
groups, cell fusion promoters, mechanical property-enhancing
groups, etc. would significantly advance performance.
Because of the variety of materials made in the group, students
utilize several analytical techniques including 1D and 2D NMR,
gel permeation chromatography, light scattering, differential
scanning calorimetry, thermal gravimetric analysis, dynamic mechanical
analysis, and electron microscopy.
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